On 1 September 2014, the Euro 6 European anti-pollution standards came
into force, and on this occasion there were new stipulations relating to the reduction
of emissions for light vehicles with a diesel engine.
See where the change is:
(Comparison between the EURO 5 and EURO 6 standards)
As can be seen in the graphics, the new EURO 6 standard has
evolved with the objective of substantially reducing nitrogen oxides (NOx).
Nitrogen oxides (NOx) and the diesel engine
The diesel engine, due to its operating characteristics, generates a high level
of
NOx, as this gas is generated under high pressure and temperature conditions.
From some time now exhaust gas treatment systems have been used, one of the
best known by professionals in the sector is the exhaust gas recirculation
system EGR, this consists of reducing the creation of nitrogen oxides (NOx), by
introducing burnt gases from the exhaust into the cylinder.
With the new emission limits required by EURO 6, many engines (especially
larger capacity engines) will not achieve the target required by the standard.
AdBlue, the solution for NOx
This technology started in the industrial, agricultural and heavy machinery
vehicle sector, and is the same system (with just small differences) that is
currently installed in passenger cars and light commercial vehicles.
AdBlue is an additive in the form of an aqueous solution made up of 32.5% urea
and 67.5% water. This is not a flammable product, it is safe to handle and in
general is not a hazardous substance for people or the environment.
The components:
Additive tank: this has a capacity of approximately 20 litres and is
usually located under the vehicle next to the fuel tank, it can also be located
in the cavity left by the spare wheel.
Internally, the tank has a built-in pump, a level gauge and an electric heating
system.
Injector: this is installed in the exhaust line, it is controlled
electrically by the control unit and is responsible for dosing the additive
directly into the exhaust.
SCR catalytic converter: This is a "Selection Catalytic
Reduction" type converter, it is a ceramic monolith inserted in the
exhaust pipe that can be located before or after the particulate filter.
SCR
catalytic converter
Warning! The SCR catalytic converter does not have
anything to do with the particulate filter:
The particulate filter (FAP) is responsible for removing the particulates.
The catalytic converter (SCR) is responsible for removing the NOx.
It facilitates the chemical reaction that will remove the nitrogen oxides
generated by the combustion of the diesel oil.
Nitrogen oxide (NOx) sensor: this sensor can detect the presence of NOx.
It is installed downstream of the SCR catalytic converter in order to verify
that there is no NOx at its outlet.
If the AdBlue system malfunctions in any way and NOx is emitted, the sensor
detects it and informs the system's control unit.
Nitrogen
oxide sensor
The NOx sensor has an integrated electronic module (inseparable
assembly).
Control unit: this is the electronic unit that manages the system. Unlike
in industrial and agricultural vehicles where this is a separate unit, in
passenger cars, the AdBlue management functions are integrated into the same
unit as that for engine control.
Operation:
The operation of the system is very simple and with few complications.
The process is started when the exhaust gas is hot (approximately 200°C), from
this moment the control unit activates the electric additive supply pump
(fitted inside the tank), which ensures the correct supply of additive to the
injector.
When the unit activates the injector's electric control, it dispenses the
amount required into the exhaust pipe (approx 1 litre of additive every 1000
km).
A chemical reaction takes place inside the exhaust pipe and the additive
(AdBlue) undergoes a transformation which produces ammonia (NH3).
The exhaust gases and the ammonia (NH3) enter the reduction catalytic converter
(SCR), the ammonia reacts with the nitrogen oxides (NOx) and transforms them
into nitrogen and water.
System settings:
The additive tank empties over the miles and the vehicle user will be informed
via a message on the instrument panel that varies depending on the range.
AdBlue information
displayed on the instrument panel
As you can see, if the driver ignores the warnings, eventually the
starting of the engine will be prevented.
Depending on the manufacturer and the current warning level, the system will
normally have to be reset by means of a suitable diagnostic tool (after filling
the additive tank).
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